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Steps were first taken towards a suitable explanation, when in 1950, Fröhlich showed that an electron-phonon interaction, where one electron emits a phonon, which is then absorbed by another, could couple two electrons together. Later that year Cooper showed that this attractive force could lead a pair of electrons to couple and have a collective energy lower than 2εf, the energy they’d have if they were individual free electrons, if they were inserted into a metal at absolute zero. The only problem was that Coopers’ theory only applied if you ignored the pairs’ interactions with the rest of the electrons in the metal. However it wasn’t until 1957 when Bardeen, Cooper & Schriefer showed that Coopers’ model for coupling of a single pair of electrons could be generalised to the 1023 electrons within a cm3.
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